Removal of 2,4-dichlorophenol and pentachlorophenol from aqueous media by electrochemical process     

Jui-Yuan Huang  Wing-Ping Liao  Siou-Mei Lai 《Environmental Earth Sciences》2013,68(8):2281-2288

Chlorophenols are persistent toxins in the natural environment. In this investigation, 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in aqueous media were degraded using an electrokinetic process (EK) and an electro-Fenton process (EF) using stainless steel and graphite as the anode and cathode, respectively. Chlorophenols were degraded via direct electrolysis at the surface of the electrode in the EK process. However, in the EF process, the degradation mechanism includes direct electrolysis and oxidation by hydroxyl radicals. The optimal conditions were a current density of 0.75 mA/cm² and an air flow of 0.7 l/min at pH 4. Under the optimal conditions, the 2,4-DCP and PCP removal rates in the EF process were 80.18 and 64.03 %, respectively. The mineralization efficiencies of 2,4-DCP and PCP were 78.23 and 75.77 %, respectively. The results of dechlorination reveal that almost all of the chlorines were released, but some were retained in the intermediates. The dechlorination efficiency revealed that the EF and EK4 processes two chlorines from 2,4-DCP. They released four or five chlorines and four chlorines from PCP, respectively. The kinetic results provide evidence of pseudo-first degradation. The rate constant (k _cp) declined as pH_i was increased from 4 to 10. The k _cp values reveal that the pH is an important factor that affects the degradation efficiency in the electrochemical process.  相似文献   

Effect of rising atmospheric CO2 on sediment and water 15N interactions in experimental riparian wetland     

Swe Hlaing Htar  Wei Zhu  Jingyu Huang  Philip Nti Nkrumah 《Environmental Earth Sciences》2013,70(7):3185-3195

The experiment was conducted to ascertain net production and consumption rates of ¹⁵NH₄ ⁺ and ¹⁵NO₃ ^? for water and sediment in a wetland. This was done using ¹⁵N isotope pool dilution methodology under ambient and elevated atmospheric CO₂ concentrations in experimental riparian wetlands to obtain the gross N transformation rates. The ¹⁵N budget for sediment was also estimated. The results suggested that the differences in high proportion of ¹⁵N concentration in the overlying water body under elevated CO₂ could be attributed to the low production and high consumption rates of ¹⁵NH₄ ⁺ in sediment. The elevated CO₂ effect on production and consumption of NH₄ ⁺ decreased by 144 % (P = 0.014) and increased by 153 % (P = 0.009), respectively. Thereby, ¹⁵NH₄ ⁺ production rates are negatively related with ¹⁵NO₃ ^? consumption rates and this accounted for the decreases in net ¹⁵NO₃ ^? consumption under CO₂ enrichment in the wetland sediment by 11 % (P = 0.528). Therefore, ¹⁵NO₃ ^? production and consumption rates may strongly depend on NH₄ ⁺ production. Inorganic ¹⁵N and total ¹⁵N exported from sediment to overlying water body by the effect of CO₂ were 41 % (P = 0.071) and 18 % (P = 0.000), respectively. Therefore, low net ¹⁵NH₄ ⁺ production and high ¹⁵NH₄ ⁺ consumption rates under elevated CO₂ may partly explain the significant reduction of N from the sediment.  相似文献   

基于转录组测序技术对调控毕加索小丑鱼(Picasso clownfish)白化体征关键基因的研究     

何丽斌  黄镇  吴水清  郑乐云 《海洋学报》2022,44(2):67-76

毕加索小丑鱼(Picasso clownfish)因其皮肤中的白色斑块分布杂乱抽象而得名,同时也由于其白色斑块的形成无规律性和稀缺性,属于名贵的小丑鱼,因此,解析毕加索小丑鱼的皮肤白斑形成机制,可以为毕加索小丑鱼的人工育种提供理论依据.在本研究中,我们对3种体色毕加索小丑鱼的背鳍和臀鳍之间的身体相同部位3种色块(黑色、...  相似文献   

四川紫色土退化的分类与分区     

黄成敏  何毓蓉  文安邦 《山地学报》1993,(4)

四川紫色土耕地面积406.1万公顷,占全省耕地面积的36.5％,属全省农业生产的主体区域。四川紫色土普遍退化。退化分为物理性(含构造性)、化学性、营养性三类。用模糊综合评判方法,评价了四川(主要为盆地丘陵区)紫色土退化的程度和状况。同时又建立了退化紫色土的分区原则,将四川紫色土退化分布区域划分为6个退化亚区,10个退化小区。  相似文献   

Advanced studies on adaptation of desert shrubs to environmental stress     

HaiXia Huang  Gang Wang  NianLai Chen 《寒旱区科学》2011,3(5):0455-0462

The combined stress of drought, high temperature and excessive light characterizes the desert area. In order to survive the desert habitat, desert shrubs have evolved a number of special eco-physiological mechanisms to resist environmental stress during long-term evolution. In this paper, adaptation mechanisms of desert shrubs to environmental stress are reviewed in terms of morphological structure, water potential, photosynthesis and water use efficiency, transpiration and stomatal conductance, osmotic adjustment and anti-oxidation protection. In addition, some suggestions for future research are proposed.  相似文献   

Cluster卫星观测的中高度极隙区中场向电流引起的磁场的扰动变化          下载免费PDF全文

张清和  刘瑞源  黄际英  刘勇华  徐中华 《极地研究》2006,18(3):175-184

本文分析了2002年9月10日Cluster四颗卫星穿越南极和北极极隙区期间的观测资料。这两次穿越是在弱而稳定的南向行星际磁场(IMF)条件下发生的。数据显示极隙区中的场向电流(FACs)引起了大的磁场扰动。本文采用了一种基于卫星多点测量来计算扰动界面方向和运动速度的方法。结果显示界面与磁力线大致平行,而它们的速度在卫星穿越南极极隙区时几乎朝向晨侧,在穿越北极极隙区时几乎朝向昏侧,并且其运动速度与相应卫星的速度相比其值很小。  相似文献   

基于GIS的中山站至Dome A冰盖考察数据处理和信息提取          下载免费PDF全文

温家洪  孙波  吴健平  范大凯  康建成  李院生  任贾文  效存德  黄声享 《极地研究》2002,14(3):203-212

中山站至DomeA冰川学考察断面是国际ITASE计划的核心断面之一。首次利用GIS开展了该断面的数据处理与信息提取 ,采样点的布设与管理。介绍了ADD数字地图拼接与裁剪 ,野外数据和BEDMAP数据地理坐标投影变换的方法。利用ArcView内插等高线方法对GPS导航仪高程数据进行了校正。沿考察路线提取了BEDMAP的冰下基岩高程和冰厚度数据 ,以及冰盖表面的坡度与坡向数据。指出应进一步开展该断面以及兰伯特冰川盆地GIS应用研究。  相似文献   

MAPGIS的数据转换与使用技巧   总被引：8，自引：0，他引：8  

黄姮 《福建地质》2004,23(3):154-159

数据的共享使用和充分利用软件的优势互补．优化数字化生产的工艺流程．是降低生产成本．提高劳动生产率的有效办法。  相似文献   

内嵌式法兰连接预制拼装双柱墩参数分析     

胡一鹏  黄遵义  曾玉昆  韩强  许坤 《震灾防御技术》2021,16(3):554-565

本文基于实际工程对内嵌式法兰连接预制拼装双柱墩参数进行了分析,将法兰设置在塑性铰区以外,设计1∶3缩尺模型,通过分析不同法兰强度等级、混凝土强度等级、轴压比和配筋率的内嵌式法兰连接预制拼装双柱墩模型,得到不同情况下推覆曲线和损伤破坏状态,分析各参数的影响。研究结果表明,法兰强度等级对结构的影响较小,配筋率对结构承载力和延性的影响较大,结构最终失效主要表现在塑性铰区域,法兰存在一定程度的翘起。  相似文献   

Lateral variation in Moho depth around the southern Tanlu fault zone and its adjacent area          下载免费PDF全文

Dequan Hong  Xianliang Huang  Yun Yang  Ziwen Bao  Xiaoli Wang  Xueying Wang 《地震科学（英文版）》2021,34(1):77-87

We estimated Moho depth beneath the southern Tanlu fault zone and its adjacent area using common-conversion-point(CCP)stacking of receiver fun-ctions,which were computed from teleseismic records of the CEArray.Our estimated Moho depth matches well with 2-D profiles derived from active-source deep seismic reflection surveys,suggesting that the calculated the Moho depth map is likely accurate beyond the 2-D profiles.Overall,the estimated Moho depth map showed a high spatial correlation with tectonic provinces,i.e.,Moho topographic boundaries are in good agreement with geological boundaries.Beneath the Dabie orogenic belt and the mountainous areas in southern Anhui Province,the Moho lies relatively deep,and there is an obvious difference in Moho depth between the two sides of this segment of the Tanlu fault.We further selected four depth profiles with dense instrumentation to show Moho depth changes across different tectonic blocks in the study area.We saw two step-like changes in Moho depth beneath the Xiangfan-Guangji and Gushi-Feizhong,which run parallel along the WNW-ESE direction and delineate the southern and northern bounds of the northern Dabie orogenic belt,which is likely the suture zone between the North China Block and South China Block.Crust beneath the northeast corner of the study area is significantly thinner than other areas,which is consistent with the crustal detachment model proposed for suturing between the North and South China blocks in the region east to the Tanlu fault.  相似文献